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Comparison of parameters of selected types of commercial lithium-ion batteries
Špina, Martin ; Libich, Jiří (referee) ; Bača, Petr (advisor)
This thesis deals with operation principles of Lithium-ion battery. It evaluates its characteristics, advantages, and disadvantages. Technological processes and materials used in manufacturing and recycling are also discussed. Practical part of the thesis evaluates initial capacity of given Li-ion cells at different loads. Batteries are then cyclically charged and discharged, and its capacity and other parameters are determined. Electrochemical impedance spectroscopy data are also taken and evaluated for batteries in new-like condition, used batteries and cycled batteries as the capacity fades.
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Study of the Ta2O5 insulating layer degradation
Velísek, Martin ; Majzner, Jiří (referee) ; Sedláková, Vlasta (advisor)
The aim of the thesis is to examine the dielectric function Ta2O5 insulating layers in tantalum capacitors. The capacitor plugged in the regular mode represents a MIS structure of reverse direction. Three different factors can be determined for the residual current of the component according to its charge transmission mode: the ohmic, Pool–Frenkel, tunnel and Schottky. An apparatus was constructed by the author of the thesis to measure the temporary connection between residual current and rise of temperature of the tantalum capacitors. Annealing of three different sets of tantalum capacitors made by different producers was performed at the temperature of 400 K and nominal voltage of 35 V during the period of 20 days.The experiment has proved the residual current in the electric field changes with rising temperature in time as a result of the ion movement. The singular factors of the residual current are influenced during the process. By the “ion movement” is meant the ion drift influenced by the attached electric field and diffusion caused by the concentration gradient. First, the samples were being annealed for c. 2 x 106 s, and then the residual current was being regenerated under the voltage of 5 V for 106 s. The residual current values increased considerably after annealing, and decreased again to more or less the original level after the regeneration, some of the samples reaching even values bellow the original level. The VA characteristics of the samples measured before and after the process of controlled obsolescence, and after the regeneration prove not only a change in parameters of the different current factors, but also a change of the current transmission mechanism employed in the process.
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Influence of thermal stress on volume and surface resistance of material
Rohel, Tomáš ; Rozsívalová, Zdenka (referee) ; Vaněk, Jiří (advisor)
This document describes the methods to test and measure the protective glasses used in solar panels. The next part of the dissertation covers the evolve summary for the norms of degradation tests. The purpose of this research is to scale the volume and surface electric resistivity of selected materials, as well as, specify the supposed durability of these materials. Evaluation of these features proceeds after enhanced aging by the use of dry heat. Samples of these materials were prepared with the cooperation of the company Solartec s.r.o
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Accelerated testing of lightfastness of indoor furniture coatings
Kulhánková, Michaela ; Drábková, Klára (referee) ; Dzik, Petr (advisor)
This bachelor thesis deals with the study of the current methods of testing and evaluation of lightfastness of interior paints. Their fading is caused mainly by the influence of solar radiation. The first part provides the basic information needed to understand the experiment. In the second part, wood samples with various white varnishes and coatings were subjected to accelerated testing of lightfastness. The experiment was performed by exposing these samples to xenon lamp through the window glass filter in the solar chamber. Changes in the color of the samples were evaluated based on the measurement of the reflection spectra from which the colorimetric quantities were calculated and then displayed in the color space CIE 1976 L*a*b*. The conclusion was focused on the final real life of the samples, their mutual comparison and evaluation of the most suitable materials.
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Degradation test of polymer material
Chleboun, Jiří ; Gvritishvili, Roman (referee) ; Vaněk, Jiří (advisor)
Basic knowledge of photovoltaic energy transformation, devices and materials, used in photovoltaics are summarized in this master’s thesis. Sort of degradation factors and its consequences of the photovoltaic panels are described there. Detail reviews of degradation tests are processed at the end of theoretical part. The main purpose of this research is selected covering materials dielectric properties change monitoring. These covering materials were influenced of accelerated thermal aging and increased humidity.
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Lightfastness of digital color prints
Kulhánková, Michaela ; Jančovičová, Viera (referee) ; Dzik, Petr (advisor)
In this diploma thesis the current methods of color fastness evaluation of color digital prints were solved. The theoretical part provides basic information needed to understand the experiment. Samples of inkjet prints were subjected to accelerated and long-term lightfastness test. The long-term test took place in the spaces of the Faculty of Chemistry, Brno University of Technology, which fulfilled the condition of direct light in a closed room. For one year, samples were exposed and their reflection spectra were measured at monthly intervals. An accelerated lightfastness test was performed in a solar chamber with a xenon lamp. Only some samples were selected for this test because of the small space in the chambre and thw failure of the instrument. At regular intervals were measured again their reflection spectra from which the colorimetric values were calculated. After completion of the testing, the rate parameter was determined from the dependence of the loss of the normalized gamut volume on different doses of irradiation. In the case of long-term testing, it was based on data from the Hydrometeorological Institute, which gave values of direct outdoor solar radiation. In the accelerated test, the irradiation dose of the sample up to 800 nm was determined. Finally, the lightfastness of each sample was examined and compared with each other and the relevance of the accelerated test was assessed.
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Influence of aging on sandwich materials properties
Smékal, Aleš ; Löffelmann, František (referee) ; Klement, Josef (advisor)
The first part of the master’s thesis deals with sandwich materials. Starting with composition of parts which the sandwich panel is made of. The thesis continues with loading distribution and testing of entire sandwich panel. The impact of environment is considered as well. The second part is its goal – determine degradation of the properties of sandwich panels with metal sheets and core after 15 years aging in the common atmosphere and aging in moistheat and salt environment by experiment.
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Enhancement of print lightfastness by varnishing and lamination
Komárková, Hana ; Reháková, Milena (referee) ; Dzik, Petr (advisor)
This diploma thesis deals with recent methods of lightfastness evaluation of both classic and digitally printed photographs. It summarizes the experimental methods used for colour change measurements. Primarily, it studies an influence of additional protection on lightfastness enhancement. Lightfastness testing of colour prints was carried out by accelerated ageing. Samples were prepared by 3 types of inkjet printers and 3 different print media. The surface of photographs was left untreated or modified by varnishing or lamination. A set of samples, thus achieved, was used to monitor a print behaviour during the light exposure. In conclusion effects of used receiving layer, ink or additional surface treatment were discussed. Colour changes were evaluated on the basis of measured reflectance spectra from which colorimetric quantities were calculated. Results were processed using VolGa application. An actual print-life was calculated from the plot of the normalized gamut volume loss and the exposure.
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